Iranian Journal of Wood and Paper Industries

Iranian Journal of Wood and Paper Industries

Investigation of physical and mechanical properties of wood plastic composite after steaming and adding recycled polymer

Document Type : Research Paper

Authors
1 Islamic Azad University, Science and Research Brananch . Tehran
2 : Department of Wood and Paper Science and Technology, Faculty of Natural Resources and Environment, Science and Research Branch, Islamic Azad University, Tehran, Iran
10.22034/ijwp.2025.2067804.1720
Abstract
Problem definition and objectives: Wood-plastic composites (WPCs) are a suitable alternative for reducing environmental pollution and managing waste due to their utilization of wood and polymeric residues. While the use of raw cellulosic fibers reduces compatibility with non-polar polymer matrices and leads to a decline in mechanical properties due to their polarity and hydroxyl groups, employing modification methods such as thermal treatment (steaming) can address these challenges. This study seeks to utilize steam treatment on poplar wood flour and recycled polypropylene, which is abundantly available in various sources. The primary objective of this research is to improve the physical and mechanical properties of wood-plastic composites, thereby producing a product of acceptable quality for industrial applications by reducing production costs and utilizing waste materials.
Methodology: To this end, Tabriz poplar wood flour was prepared and subjected to steam treatment at 180°C for one hour. For composite fabrication, virgin and recycled polypropylene were used alongside maleic anhydride as a coupling agent. Materials were mixed in an internal mixer based on specific weight ratios (40% wood flour and 60% polymer), and samples were prepared using injection molding. Prior to testing, samples were conditioned under standard environmental conditions (23°C temperature and 50% relative humidity). To determine physical and mechanical characteristics, tests for water absorption, thickness swelling, tensile strength, flexural strength, and impact strength were conducted. Additionally, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD) were employed for structural analysis.
Results: Regarding physical properties, the lowest water absorption and thickness swelling were observed in samples containing steamed fibers and virgin polymer. These results indicate the removal of some hemicelluloses and a reduction in hydroxyl groups due to steaming, leading to increased hydrophobicity. In terms of mechanical properties, the highest tensile, flexural, and impact strengths were found in samples made from steamed poplar wood flour and virgin polypropylene. Scanning electron microscopy images demonstrated better distribution and superior adhesion between steamed fibers and the polymer matrix. FTIR results indicated a decrease in the intensity of peaks related to hydroxyl groups and the degradation of hemicelluloses. Although the use of recycled polymer caused a slight decrease in properties, this difference was not statistically significant.
Conclusion: The results showed that steaming reduced water absorption and thickness swelling while enhancing mechanical properties. The most significant finding was the improvement in adhesion between the fiber phase and the polymer due to the removal of hemicelluloses. In addition to improving physical properties, combining steamed wood flour with virgin polypropylene increased mechanical strengths. Furthermore, while the use of recycled polymer was accompanied by a slight decrease in properties, it is of industrial and economic importance due to its environmental benefits and cost reduction, and can serve as a suitable alternative when combined with virgin polymer.
Keywords

Subjects


[1] Kinoshita, Y., Yamada, T., Gupta, S.M., Ishigaki, A. and Inoue, M. (2020) “Decision support model of environmentally friendly and economical material strategy for life cycle cost and recyclable weight”, International Journal of Production Economics, 224(C), p. 107545. Doi: 10.1016/j.ijpe.2019.107545.
[2] Lopez, Y.M., Paes, J.B., Gustave, D., Gonçalves, F.G., Méndez, F.C. and Nantet, A.C.T. (2020) “Production wood-plastic composites using cedrela odorata sawdust waste and recycled thermoplastics mixture from post-consumer products-A sustainable approach for cleaner production in Cuba”, Journal of Cleaner Production, 244(2), p. 118723. Doi: 10.1016/j.jclepro.2019.118723.
[3] Iakovlev, M., Survase, S., Segers, P., Sideri, S., Rouzinou, S., Pylkkanen, V. and Retsina, T. (2020) “Sulfur dioxide-ethanol-water fractionation platform for conversion of recycled wood to sugars, lignin and lignosulfonates”, Bioresource Technology, 300, p. 122652. Doi: 10.1016/j.biortech.2019.122652.
[4] Altuntaş, E., Yilmaz, E., Salan, T. and Alma, M.H. (2017) “Combined effect of zinc borate and coupling agent against brown and white rot fungi in wood-plastic composites”, BioResources, 12(4), pp. 7056-7068.
[5] Lopez, M.D.M.C., Pernas, A.I.A., Lopez, M.J.A., Latorre, A.L., Vilariño, J.L. and Rodríguez, M.V.G. (2014) “Assessing changes on poly (ethylene terephthalate) properties after recycling: Mechanical recycling in laboratory versus postconsumer recycled material”, Materials Chemistry and Physics, 147(3), pp. 884-894. Doi: 10.1016/j.matchemphys.2014.06.003.
[6] Bal, B. (2022) “Mechanical properties of wood-plastic composites produced with recycled polyethylene, used Tetra Pak® boxes, and wood flour”, BioResources, 17(4), pp. 6569-6577. doi:10.15376/biores.17.4.6569-6577.
[7] Krause, K.C., Sauerbier, P., Koddenberg, T. and Krause, A. (2018) “Utilization of recycled material sources for wood-polypropylene composites: Effect on internal composite structure, particle characteristics and physico-mechanical properties”, Fibers, 6(4), p. 86. Doi:10.3390/fib6040086.
[8] Jamekhorshid, A., Sadrameli, S.M., Barzin, R. and Farid, M.M. (2017) “Composite of wood-plastic and micro-encapsulated phase change material (MEPCM) used for thermal energy storage”, Applied Thermal Engineering, 112, pp. 82-88. Doi: 10.1016/j.applthermaleng.2016.10.041.
[9] Dairi, B., Djidjelli, H., Boukerrou, A., Migneault, S. and Koubaa, A. (2017) “Morphological, mechanical, and physical properties of composites made with wood flour‐reinforced polypropylene/recycled poly (ethylene terephthalate) blends”, Polymer Composites, 38(8), pp. 1749-1755. Doi:10.1002/pc.23741.
[10] Bouhamed, N., Souissi, S., Marechal, P., Amar, M.B., Lenoir, O., Leger, R. and Bergeret, A. (2020) “Ultrasound evaluation of the mechanical properties as an investigation tool for the wood-polymer composites including olive wood flour”, Mechanics of Materials, 148, p. 103445. Doi: 10.1016/j.mechmat.2020.103445.
[11] Moreno, D.D.P. and Saron, C. (2017) “Low-density polyethylene waste/recycled wood composites”, Composite Structures, 176, pp. 1152-1157. Doi: 10.1016/j.compstruct.2017.06.025.
[12] Li, X., Lei, B., Lin, Z., Huang, L., Tan, S. and Cai, X. (2014) “The utilization of bamboo charcoal enhances wood plastic composites with excellent mechanical and thermal properties”, Materials & Design, 53, pp. 419-424. Doi: 10.1016/j.matdes.2013.07.040.
[13] Khan, A., Mishra, A., Thakur, V. and Pappu, A. (2025) “Towards sustainable wood plastic composites: polymer types, properties, processing and future prospects”, RSC Sustainability, pp. 2833-2862.
[14] Guo, X., Fu, Y., Zhang, F., Li, X. and Liu, N. (2021) “Change of structural features and relocalization of chemical components in the autohydrolyzed poplar wood chips enhance the accessibility of remaining components”, Industrial Crops and Products, 167, p. 113508. Doi: 10.1016/j.indcrop.2021.113508.
[15] Brodowsky, H. and Mäder, E. (2018) “Investigation of transcrystalline interphases in polypropylene/glass fiber composites using micromechanical tests”, Fibers, 6(1), p. 16. Doi:10.3390/fib6010016.
[16] Friedrich, D. (2024) “Branding of wood-plastic composites under generic name “Biobased-Plastic” or specifically as “Wood-Plastic Composite”? A consumer study under compolytics approach”, Journal of Cleaner Production, 470, p. 143276. Doi: 10.1016/j.jclepro.2024.143276.
[17] Voltz, L., Guiseppe, I., Geng, S. and Oksman, K. (2020) “The effect of recycling on wood-fiber thermoplastic composites”, Polymers, 12(8), p. 1750. Doi:10.3390/polym12081750.
[18] Toscano, G., Maceratesi, V., Leoni, E., Stipa, P., Laudadio, E. and Sabbatini, S. (2022) “FTIR spectroscopy for determination of the raw materials used in wood pellet production”, Fuel, 313, p. 123017. Doi: 10.1016/j.fuel.2021.123017.
[19] Chaudhary, V., Ram, K. and Ahmad, F. (2019) Reinforced Polymer Composites. 1st edn. New Delhi: Wiley-VCH.
[20] Lazrak, C., Kabouchi, B., Hammi, M., Famiri, A. and Ziani, M. (2019) “Structural study of maritime pine wood and recycled high-density polyethylene (HDPEr) plastic composite using Infrared-ATR spectroscopy, X-ray diffraction, SEM and contact angle measurements”, Case Studies in Construction Materials, 10, e00227. Doi: 10.1016/j.cscm. 2019.e00227.
[21] Mertens, O., Krause, K.C. and Krause, A. (2018) “Evaluation of wood fiber composites based on a novel simultaneous defibration and compounding process”, Journal of Applied Polymer Science, 135(7), p. 45859. Doi:10.1002/app.45859.
[22] Hojaholeslami, Z., Bagherzadeh, E. and Zebarjad, M. (2020) “Making high-density polyethylene wood-plastic composite of poplar wood and investigating its mechanical, thermal and morphological properties”. In: 9th International conference on
materials engineering and metallurgy. Tehran, 10-11 November. [In Persian].
[23] Bashardoust, Z., Hedjazi, S. and Hamzeh, Y. (2025) “Production of Chemical Pulp Using Carbonate Process from Wheat Straw”, Iranian Journal of Wood and Paper Industry, 16(1), pp. 1-14. Doi:10.22034/ijwpi.2025. [In Persian].
[24] Gholami, M., Mansori, H. and Nosrati, B. (2015) “Investigation of the Physical Properties of Wood Plastic Composite made from recycled materials”. In: Collected Papers of the First National Symposium on Wood and Lignocellulosic products. [In Persian].