Iranian Journal of Wood and Paper Industries

Iranian Journal of Wood and Paper Industries

Possibility of producing wooden objects by pressure molding through treatment with ‎hydrogen peroxide and hygrothermal treatment

Document Type : Research Paper

Authors
1 PhD candidate
2 Associate Professor, Department of Wood and Paper Science & Technology, Faculty of Natural Resources, University of Tehran, Karaj, Iran
3 Department of Wood and Forest Technology, University of Linnaeus, Sweden.‎
4 Department of wood and paper science and technology
5 M.S in Polymer Chemistry University of Isfahan
10.22034/ijwp.2024.2024630.1649
Abstract
Problem definition and objectives: The processes of producing wooden products are not so diversative like the ones used for metals and plastics and usually have large amount of waste. Molding is one of the most commonly used methods by manufacturers of metal and plastic products. Molding is one of the methods that reduce waste and costs and at the same time increases the efficiency and production speed. In this context, the use of molding for wooden products seems somewhat unlikely due to the physical properties of wood. Wood does not melt from heat, and it cannot easily be shaped within a mold. The aim of this study is to investigate the mass production of wooden components using the compression molding method with poplar wood species.
Methodology: This research was conducted in four main stages: initial chemical treatment, thermal steam treatment, mold shaping, and final thermal treatment to stabilize the shape. The chemical treatment with hydrogen peroxide was used to relatively remove lignin and initially soften the wood texture. To this end, the samples were saturated with hydrogen peroxide under vacuum and pressure at different time intervals. The amount of lignin removal was assessed using microscopic studies and infrared spectroscopy. In the next stage, to enhance flexibility and facilitate easier molding, the saturated samples were subjected to hygrothermal treatment at 180°C for three hours. A controlled temperature hot mold was utilized to create the final product in the shape of a small container. During molding, the temperature was set at 180°C. In the final stage, after shaping, the formed wooden product was kept in the mold at same temperature for an additional two hours to ensure drying and stabilization of its dimensions. Finally, some physical properties of the formed product were studied.
Results: The obtained results confirmed that there is a possibility of producing formed wood pieces using this method. Microscopic studies also showed that treatment with hydrogen peroxide leads to the relative removal of lignin from the wood. These results were also supported by data from infrared spectroscopy and thermogravimetric analysis. The dry density of the control poplar wood was ±0.41 g/cm³, which increased to ±0.57 g/cm³ due to processing. Water absorption in the shaped samples was very rapid during the first two hours of immersion in water, but it then decreased and showed little change over the following 144 hours. The maximum water absorption of these samples after six days of immersion in water was 32% less than that of the control sample. The pattern of dimensional changes of the samples obtained from molded pieces was also different from that of the control poplar wood in various directions. The maximum transverse shrinkage of the molded samples was 19.3% less than that of the control poplar wood. On the other hand, the differences in shrinkage in width and thickness of the molded samples were much less than those of the control sample.
Conclusion: Although the results of this research were promising for the mass production of wooden subjects using the compression molding method, there are cracks on the final product that require further studies for resolution. The chemical treatment of wood with hydrogen peroxide and steam heating treatment provides the capability for softening the wood texture and shaping it within the mold. According to the results of this study, waste wood from sawmills and furniture factories, which cannot be used due to its small size, can be utilized for the mass production of wooden products without the need for shredding.
Keywords

Subjects


[1] Kamal, M. R., Isayev, A. I. and Liu, S. J. 2009. Injection Molding. Technology and Fundamentals. Munich Germany, 950 Pages. 
[2]  Reinprecht, L. 2016. Wood deterioration, protection, and maintenance. London: Wiley Blackwell. 384 Pages.
[3]  Fengel, D. and Wegener, G. 2011. Wood: chemistry, ultrastructure, reactions. Walter de ‎Gruyter, Walter de Gruyter, Berlin and New York. 618 Pages.
[4]  Li, W., Sun, N.,  Stoner, B.,  Jiang, X., Lu, X. and Rogers, R. D. 2011. Rapid dissolution of lignocellulosic biomass in ionic liquids using temperatures above the glass transition of lignin. Green Chemistry, 13 (8), pp. 2038–2047.
[5]  Blechschmidt, J., Engert, P. & Stephan, M. 1986. The glass transition of wood from the viewpoint of mechanical pulping. Wood Sci.Technol. 20, 263–272.
[6]  Ibach, R. 2021. Specialty treatments. Chapter 19 in FPL-GTR-282, 19-1.
[7]  Gašparík, M. and Barcík, Š., 2014. Effect of plasticizing by microwave heating on bending characteristics of beech wood. BioResources, 9(3), pp.4808-4820.
[8]  de Peres, M.L., de Ávila Delucis, R., Gatto, D.A. and Beltrame, R., 2016. Mechanical behavior of wood species softened by microwave heating prior to bending. European Journal of Wood and Wood Products, 74, pp.143-149.
[9]  Suleman, Y.H., 2015. Softening and bending of black poplar (Populus nigra L.) wood with chemicals. Tikrit Journal for Agricultural Sciences, 15(4), pp. 15-20.
[10]         Zhang, D., Zhang, A. and Xue, L., 2015. A review of preparation of binder less fiberboards and its self-bonding mechanism. Wood Science and Technology, 49, pp.661-679.
[11]         BARISKA, M. and SCHUERCH, C. 1977. Wood Softening and Forming with Ammonia. Wood Technology: Chemical Aspects, 21, 326-347pp.
[12]         Zhao, C., Qiao, X., Shao, Q., Hassan, M., Ma, Z. and Yao, L., 2020. Synergistic effect of hydrogen peroxide and ammonia on lignin. Industrial Crops and Products, 146, p.112177.
[13]         Lucas, M., Hanson, S.K., Wagner, G.L., Kimball, D.B. and Rector, K.D., 2012. Evidence for room temperature delignification of wood using hydrogen peroxide and manganese acetate as a catalyst. Bioresource technology, 119, pp.174-180.
[14]         Sandberg, D., Haller, P. and Navi, P., 2013. Thermo-hydro and thermo-hydro-mechanical wood processing: An opportunity for future environmentally friendly wood products. Wood Material Science & Engineering, 8(1), pp.64-88.
[15]         Navi, P. and Heger, F., 2004. Combined densification and thermo-hydro-mechanical processing of wood. MRS bulletin, 29(5), pp.332-336.
[16]         Bari, E., Karim, M., Oladi, R., Tajick Ghanbary, M.A., Ghodskhah Daryaei, M., Schmidt, O., Benz, J.P. and Emaminasab, M., 2017. A comparison between decay patterns of the white‐rot fungus Pleurotus ostreatus in chestnut–leaved oak (Quercus castaneifolia) shows predominantly simultaneous attack both in vivo and in vitro. Forest Pathology, 47(4), p.e12338.
[17]         Smith, J.M., Van Ness, H.C., Abbott, M.M. and Swihart, M.T., 2018. Introduction to chemical engineering thermodynamics. Singapore: McGraw-Hill.
[18]         Oladi, R., Pourtahmasi, K., Eckstein, D. and Brauning, A., 2010. Study of xylem lignification in oriental beech (Fagus orientalis Lipsky) along an altitudinal gradient. Iranian Journal of Natural Resources, 63(3), pp.215-227.
[19]         Peters, F.B. and Rapp, A.O., 2022. Wavelength-dependent photodegradation of wood and its effects on fluorescence. Holzforschung, 76(1), pp.60-67.
[20]         Zhuang, J., Li, M., Pu, Y., Ragauskas, A.J. and Yoo, C.G., 2020. Observation of potential contaminants in processed biomass using fourier transform infrared spectroscopy. Applied Sciences, 10(12), p.4345.
[21]         Gupta, B.S., Jelle, B.P. and Gao, T., 2015. Wood facade materials ageing analysis by FTIR spectroscopy. Proceedings of the Institution of Civil Engineers-Construction Materials, 168(5), pp.219-231.
[22]         Ganne-Chédeville, C., Jääskeläinen, A.S., Froidevaux, J., Hughes, M. and Navi, P., 2012. Natural and artificial ageing of spruce wood as observed by FTIR-ATR and UVRR spectroscopy.
 
[23]         Xiong, X.Q., Bao, Y.L., Liu, H., Zhu, Q., Lu, R. and Miyakoshi, T., 2019. Study on mechanical and electrical properties of cellulose nanofibrils/graphene-modified natural rubber. Materials Chemistry and Physics, 223, pp.535-541.
[24]         Wójciak, A., Kasprzyk, H., Sikorska, E., Khmelinskii, I., Krawczyk, A., Oliveira, A.S., Ferreira, L.F. and Sikorski, M., 2010. Changes in chromophoric composition of high-yield mechanical pulps due to hydrogen peroxide bleaching under acidic and alkaline conditions. Journal of Photochemistry and Photobiology A: Chemistry, 215(2-3), pp.157-163.
[25]         Moosavi Nejad, S.M., Madhoushi, M., Rasouli, D. and Vakili, M., 2017. Nondestructive evaluation of wood chemical compounds used in Gorgan historical building via FT-IR spectroscopy. Journal of Wood and Forest Science and Technology, 23 (1), pp.313-328.
[26]         Popović, J., Svrzić, S., Gajić, M., Maletić, S., Dodevski, V., Djiporović-Momčilović, M., Krstić, S. and Popović, M., 2022. Light transmittance of mahogany wood treated with 20% hydrogen peroxide solution. BioResources, 17(4), p.5919.
[27]         Sebio-Punal, T., Naya, S., López-Beceiro, J., Tarrío-Saavedra, J. and Artiaga, R., 2012. Thermogravimetric analysis of wood, holocellulose, and lignin from five wood species. Journal of Thermal Analysis and Calorimetry, 109(3), pp.1163-1167.
[28]         Slopiecka, K., Bartocci, P. and Fantozzi, F., 2012. Thermogravimetric analysis and kinetic study of poplar wood pyrolysis. Applied Energy, 97, pp.491-497.
[29]         Baysal, E., Deveci, I., Turkoglu, T. and Toker, H., 2017. Thermal analysis of oriental beech sawdust treated with some commercial wood preservatives. Maderas. Ciencia y tecnología, 19(3), pp.329-338.
[30]         Nurazzi, N., Asyraf, M.R.M., Rayung, M., Norrrahim, M.N.F., Shazleen, S.S., Rani, M.S.A., Shafi, A.R., Aisyah, H.A., Radzi, M.H.M., Sabaruddin, F.A. and Ilyas, R.A., 2021. Thermogravimetric analysis properties of cellulosic natural fiber polymer composites: A review on influence of chemical treatments. Polymers, 13(16), p.2710.