مجله صنایع چوب و کاغذ ایران

مجله صنایع چوب و کاغذ ایران

بررسی امکان تولید مستقیم پلیمر استات سلولز از اسکناس های باطله

نوع مقاله : مقاله پژوهشی

نویسندگان
1 دانشگاه تهران
2 دانشکده منابع طبیعی دانشگاه تهران
3 دانشگاه علوم کشاورزی و منابع طبیعی گرگان
چکیده
با توجه به حجم زیاد ضایعات اسکناس‌های باطله و هزینه‌های بالای امحاء و نیز آلودگی‌های زیست محیطی ناشی از آن، امکان تبدیل این ضایعات به محصولاتی مانند پلیمر‌های استات سلولز که از لحاظ اقتصادی مقرون به صرفه بوده و همچنین فرآیند تولید آنها با کمترین آلودگی های زیست محیطی همراه باشد، از اهمیت بالایی برخوردار است. در این مقاله،به منظور دستیابی به استات سلولز پس از رنگبری اسکناس‌ها ، فرآیند استیلاسیون با استفاده از اسید استیک به عنوان حلال، اسید سولفوریک به عنوان کاتالیزور و انیدرید استیک صورت پذیرفت. بازده درصد استیلاسیون با افزایش زمان واکنش و دما افزایش یافت و در دمای ۵۵ درجه سانتی گراد حداکثر بازده بدست آمد. غلظت استیک انیدرید، سولفوریک اسید به عنوان کاتالیزور سبب تغییر درجه جایگزینی پلیمر استات سلولز گردید. تصاویرمیکروسکوپ الکترونی روبشی نشان داد که قطر الیاف استات سلولز در مقایسه با سلولز خالص ( اسکناس باطله) کاهش یافته است. نتایج طیف سنج مادون قرمز تبدیل فوریه نشان داد که عملاً مقدار قابل توجهی گروه‌های هیدروکسیل با گروه‌های استات جایگزین شدند. الگوهای پراش اشعه ایکس نمونه اسکناس رنگبری شده پس از فرآیند استیلاسیون تغییر کرد که در کاهش قله در موقعیت 23 نمونه قبل و بعد از استیلاسیون مشهود است.
کلیدواژه‌ها

موضوعات


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