Collapsibility and Wettability of Hydrothermally Treated Wood

Document Type : Research Paper

Authors

Abstract

Study on collapsibility of oriental beech (Fagus orientalis) and paulownia (Paulownia fortune) woods due to their hydrothermal modification as well as the wettability and the water absorption were the main concerns of this research work. Out of these species, blocks of sizes 50×6×6cm were prepared and treated at temperatures of 130 and 150°C with a holding time of 30min in a stainless steel reactor containing the water. Oven dried weights and dimensions of the blocks were measured before and after the hydrothermal treatment to determine the density, collapsibility and mass loss due to applied treatment. Furthermore, small blocks of the treated wood were prepared and soaked in water for 1000-hr to determine their water absorption. The wettability of the woods were also measured to determine the water repellency. Results revealed that any raise of treatment temperature up to 150°C increases the density and the collapsibility. Treated wood collapsed in all directions; however, tangential collapse was much worse than the other directions. The contact angle was increased by rise of the treatment temperature. Hydrothermal treatment has reduced water absorption and increased the hydrophobicity of the woods.
 

Keywords


1- Anonymous, 2002. The Plato technology: A novel wood upgrading technology, Online at: www.platwood.nl.
2- American Society for Testing of Materials, ASTM D 2395-02, 2003. Standard test methods for specific gravity of wood and wood-based materials.
3- Ayrilmiş, N., Laufenberg, T.L. and Winandy, J. E., 2009. Dimensional stability and creep behavior of heat treated exterior medium density fiberboard, European Journal of Wood Products, Vol. 67: 287-295.
4- Bhuiyan, M.R.T., Hirai, N., and Sobue, N., 2002. Changes of crystallinity in wood cellulose by heat treatment under dried and moist conditions, Wood Science, Vol. 46: 431-436.
5- Boonstra, M.J., Rijsdijk, J.F., Sander, C., Kegel, E., Tjeerdsma, B., Militz, H., van Acker, J. and Stevens, M., 2006a. Microstructural and physical aspects of heat treated wood. I. Softwoods, Maderas. Cienca Y Tecnologia, Vol. 8 (3):193-208.
6- Boonstra, M.J., Rijsdijk, J.F., Sander, C., Kegel, E., Tjeerdsma, B., Militz, H. and van J. Stevens M., 2006b: Microstructural and physical aspects of heat treated wood. II. Hardwoods, Maderas. Cienca Y Tecnologia Vol. 8 (3): 209-217.
7- Boonstra, M.J. and Tjeerdsma, B., 2006. Chemical analysis of heat treated softwoods, Holz als Roh- Und Werkstoff, Vol. 64 (3): 204-211.
8- Christiansen, A.W., 1990. How overdrying wood reduces its bonding to phenol formaldehyde adhesives: a Critical Review of the literature. Part I. Physical responses, Wood and Fiber Science, Vol. 22: 441-459.
9- Esteves, B., Marques, A.V., Domingis, I. and Pereira, H., 2007. Influence of steam heating on the properties of pine and eucalypt woods, Wood and Science Technology, Vol. 41: 193-207.
10- Garrote, G., DomõÂnguez, H. and Parajo, J.C., 1999. Hydrothermal processing of lignocellulosic materials; Holz als Roh- und Werkstoff, Vol. 57 (3): 191-202.
11- Gündüz, G., Aydemir, D. and Karakas, G., 2009. The Effect of thermal treatment on the mechanical properties of wild pear (Pyrus elaeagnifolia) wood and changes in physical properties, Materials and Design, Vol. 30: 4391-4395.
12- Hillis, W.E., 1984. High temperature and chemical effects on wood stability, Wood Science and Technology, Vol. 18: 281-293.
13- Kelley, S.S., Rials, T.G. and Glasser, W.G., 1987. Relaxation behavior of the amorphous components of wood, Journal of Materials Science, Vol. 22: 617-624.
14- Kubojima, Y. and Ohta, M., 2000. Bending strength and toughness of heat treated wood, Journal of Wood and Fiber Science, Vol. 46: 8-15.
15- Metsa-Kortelainen, S., Antikainen, T. and Vittaniemi, P., 2005. Water absorption of sapwood and heartwood of Scots pine and Norway spruce heat treated at 170°c, 190°c and 230°c, Holz als Roh-und Werkstoff, Vol. 64: 192-197.
16- Mohebby, B. and Sanaei, I., 2005. Influence of hydrothermal treatment on physical properties of beech wood, The International Research Group on Wood Preservation, IRG Document No. IRG/WP 05-40303.
17- Mohebby, B., Fallah-Moghadam, P., Ghotbifar, A. R. and Kazemi-Najafi, S., 2011: Influence of Maleic-Anhydride-Polypropylene (MAPP) on Wettability of Polypropylene/Wood Flour/GlassFiber Hybrid Composites, J. Agri. Sci., Vol. 13: 877-884. 
18- Poncsak, S., Kocaefe, D., Gastonguay, L. and Younsi, R., 2006. Thermal treatment of electrical poles, Wood Science and Technology, Vol. 43: 471-486. 
19- Santos, J.A., 2000. Mechanical behaviour of eucalyptus wood modified by heat, Wood Science and Technology, Vol. 34: 39-42.
20- Sundquvist, B., Westermark, U. and Eriksson G., 2006a. Degradation of cellulose during hydrothermal treatment of wood (Betula pubescens Enrh.), Cellulose Chemistry and Technology, Vol. 40 (3): 217-221.
21- Sundquvist, B., Karlsson, O. and Westermark, U., 2006b. Determination of formic acid concentrations formed during hydrothermal treatment of birch wood and its relation to colour, strength and hardness, Wood Science and Technology, Vol. 40 (7): 549-561.
22- Tjeerdsma, B.F. and Militz, H., 2005. Chemical changes in hydrothermal treated wood: FTIR analysis of combined hydrothermal and dry heat-treated wood, Holz als Roh-und Werkstoff, Vol. 63(2): 102-111.
23- Weiland, J.J. and Guyonnet, R., 2003. Study of chemical modification and fungi degradation of thermally modified wood using DRIFT spectroscopy, Holz  als Roh- und Werkstoff, Vol. 61: 216-220. 
24- Winandy, J.E. and Smith, W.R., 2006. Enhancing composite durability: Using thermal treatments, In: Barnes, H.M. (ed.), Proceed. Wood Protection, March 21–23, Forest Products Society, New Orleans, Louisiana, pp 195–199.
25- Yildiz, S. and Gümüşkaya, E., 2007. The effect of thermal modification on crystalline structure of cellulose in soft and hardwood, Building and Environment Vol. 42(4): 62-67.