Investigation of the physical, mechanical and morphological properties of the foam obtained from polylactic acid and microcrystalline cellulose

Document Type : Research Paper

Authors

1 Academic Staff Member at University of Zabol

2 P.hD student

3 Department of wood and paper science

4 Academic Staff Member at University of Zabol.

10.22034/ijwp.2023.2002991.1614

Abstract

Foams made from poly-lactic acid, which is a natural polymer, have been introduced as an alternative to petroleum-based foams. However, the use of these foams faces limitations in terms of physical and mechanical characteristics. To improve the quality of poly-lactic acid foams, natural nucleating agents such as cellulose derivatives can be used. The effect of micro-crystalline cellulose as a nucleating agent in the production of poly-lactic acid/wood flour foam with azodicarbonamide foaming agent was investigated. The results revealed that by increasing the foaming agent content up to 3% and the nucleating agent content up to 4%, the density of the foam panels decreased by 45.52%. The reduction in density was accompanied by an increase in porosity, expansion rate, water absorption, and thickness swelling throughout all treatment levels (1 to 3% foaming agent and 1 to 4% nucleating agent), and this decrease in density led to a reduction in tensile and flexural strength and an increase in impact resistance. The morphological changes of the produced foams were also confirmed by scanning electron microscopy (SEM) images.

Keywords

Main Subjects


[1] Hamad, K., Kaseem, M., Yang, H., Deri, F. and Ko, Y., 2015. Properties and medical applications of polylactic acid: A review. Express polymer letters 9(5).
   [2] Chen, Y., Geever, L.M., Killion, J.A., Lyons, J.G., Higginbotham, C.L. and Devine, D.M., 2016. Review of multifarious applications of poly (lactic acid). Polymer-Plastics Technology and Engineering 55(10):1057-1075.
   [3] Teixeira, E.d.M., De Campos, A., Marconcini, J., Bondancia, T., Wood, D., Klamczynski, A., Mattoso, L. and Glenn, G., 2014. Starch/fiber/poly (lactic acid) foam and compressed foam composites. RSC Advances 4(13):6616-6623.
   [4] Parker, K., Garancher, J.-P., Shah., S. and Fernyhough. A., 2011. Expanded polylactic acid-an eco-friendly alternative to polystyrene foam. Journal of Cellular Plastics 47(3):233-243.
   [5] Nofar, M., and Park, C.B., 2014. Poly (lactic acid) foaming. Progress in Polymer Science 39(10):1721-1741.
   [6] Ren, Q., Wu, M., Wang, L., Zheng, W., Hikima, Y., Semba, T., and Ohshima, M., 2022. Cellulose nanofiber reinforced poly (lactic acid) with enhanced rheology, crystallization and foaming ability. Carbohydrate Polymers 286:119320.
   [7] Ding, W., Kuboki, T., Wong, A., Park, C.B. and Sain, M., 2015. Rheology, thermal properties, and foaming behavior of high d-content polylactic acid/cellulose nanofiber composites. RSC advances 5(111):91544-91557.
   [8] Reglero Ruiz, J.A., Vincent,  M., Agassant, J.F., Sadik, T., Pillon, C. and Carrot, C., 2015. Polymer foaming with chemical blowing agents: Experiment and modeling. Polymer Engineering & Science 55(9):2018-2029.
   [9] Coste, G., Negrell, C. and Caillol, S., 2020. From gas release to foam synthesis, the second breath of blowing agents. European Polymer Journal 140:110029.
   [10] Motloung, M.P., Ojijo, V., Bandyopadhyay, J. and Ray, S,S., 2019. Cellulose nanostructure-based biodegradable nanocomposite foams: a brief overview on the recent advancements and perspectives. Polymers 11(8):1270.
   [11] Dahmardeh Ghalehno, M. and Kord, B., 2021. Preparation, characterization and performance evaluation of wood flour/HDPE foamed composites reinforced with graphene nanoplatelets. Journal of Composite Materials 55(4):531-540.
   [12] Kord, B. 2012. Preparation and characterization of lignocellulosic material filled polyethylene composite foams. Journal of Thermoplastic Composite Materials 25(8):917-926.
   [13] Hassan, N.A.A., Ahmad, S., Chen, R.S. and Shahdan, D., 2020. Cells analyses, mechanical and thermal stability of extruded polylactic acid/kenaf bio-composite foams. Construction and Building Materials 240:117884.
   [14] Gwon, J.G., Lee, S.Y., Kang, H. and Kim, J.H., 2012. Effects of sizes and contents of exothermic foaming agent on physical properties of injection foamed wood fiber/HDPE composites. International Journal of Precision Engineering and Manufacturing 13:1003-1007.
   [15] Zong, Q., Xu, A., Chai, X., Zhang, Y. and Song, Y., 2020. Increased expansion ratio, cell density, and compression strength of microcellular poly (lactic acid) foams via lignin graft poly (lactic acid) as a biobased nucleating agent. Polymers for Advanced Technologies 31(10):2239-2249.
   [16] Ge, Z., Qi, D. Si. and M. Yu., 2018. The effects of processing parameters and ac foaming agent on the mechanical properties and morphology of foamed wood-polylactic acid (PLA) composites. BioResources 13(1):1605-1618.