Investigation on coating of paper with biodegradable polymers and Zinc Oxide nanoparticles on its mechanical and barrier properties

Document Type : Research Paper

Authors

1 Assistant Prof., Research Group of Cellulosic Materials and Packaging, Research Department of Chemistry and Petrochemistry, Standard Research Institute, Iran

2 Assistant Prof. Research Group of Cellulosic Materials and Packaging, research Department of Chemistry and Petrochemistry , Standard Research Institute, Iran

10.22034/ijwp.2023.1996426.1604

Abstract

This research has been carried out to determine the effects of coating of paper with biodegradable polymers and zinc oxide nanoparticles on its mechanical and barrier properties. Zinc oxide nanoparticles were synthesized by solid-state reaction method and where characterized and analyzed by XRD, SEM and TEM techniques. The results showed that the zinc oxide nanoparticles had a suitable and relatively uniform granulation and had Wurtzite hexagonal morphology. Biodegradable polymers of polyvinyl alcohol, carboxymethylcellulose, starch and a mixture of them with and without zinc dioxide nanoparticles were used to coat the paper at a gramage of 20 g / m2. Barrier properties of coated paper such as air permeability (Gurley), water vapor transmission rate (WVTR) and oxygen transmission rate (OTR) were measured. The results showed that coating the paper with polymer and zinc oxide nanoparticles improved the barrier properties. The mechanical properties of the samples were investigated by performing static tensile and burst resistance test. The results showed that the mechanical properties of the samples increased due to the coating, so that the treatment of a mixture of polyvinyl alcohol, carboxymethylcellulose and starch with zinc oxide nanoparticles had the highest results.

Keywords

Main Subjects


[1] Coles, R., McDowell, D. and Kirwan, M.J., 2003 .Food packaging technology. Oxford, U.K.: Blackwell Publishing. p 284.
[2] Kopacic, S., Walzl, A., Zankel, A., Leitner, E. and Bauer, W., 2018. Alginate and chitosan as a functional barrier for paper-based packaging materials. Coatings, 8:235-250.
[3] Ali, R. R., Rahman, W. W. A., Kasmani, R. M. and Ibrahim N., 2012. Starch based biofilms for green packaging. Internation Journal of Chemical, Molecular, Materials and Metallurgical Engineering, 6: 937-941.
[4] Leja, K. and Lewandowicz, G., 2010. Polymer biodegradation and biodegradable polymers. Polish Journal of Environment, 19: 255-266.
[5] Sharma, A., Kumawat, A., Chattopadhyay, S., Kanwar Khangarot, R.,  Misra R.D.K. and Misra, K. P., 2022 . Low temperature induced red-shift in violet-blue emission from Zn(Al, Ag)O nanoparticles. Advanced Performance Materials, 37: 1629-1638.
[6] Hu,X. L., Zhu, Y. J. and Wang, S. W., 2004. Sonochemical and microwave-assisted synthesis of linked single-crystalline ZnO rods. Advanced Performance Materials, 37: 1629-1638.
[7] Jiang, J., Pi, J. and Cai, J., 2018 . The Advancing of Zinc Oxide Nanoparticles for Biomedical Applications. Bioinorganic Chemistry and Applications. Volume 2018 | Article ID 1062562  https://doi.org/10.1155/2018/1062562.
[8] Dehghani Firouzabadi, M. R. and Aliabadi, M., 2023 . The comparison of coated paper properties with cellulose nanofiber-zinc nanooxide and starch zinc nanooxide. Journal of forest and wood product, 75(4): 377-386, (In Persian).
[9] Agarwal, H., Venkat Kumar, S. and Rajeshkumar, S., 2017 . A review on green synthesis of zinc oxide nanoparticles – An eco-friendly approach. Resource-Efficient Technologies, 3:)4(,406-413
[10] Shi, L. E., Li, Z. H., Zheng, W., Zhao Y. F., Jin, Y. F. and Tang, Z. S., 2017 . Synthesis, antibacterial activity, antibacterial mechanism and food applications of ZnO nanoparticles: a review. Food Additives & Contaminants: Part A, 31: 173-186
[11] Nazarnezhad, N., Mohammadi, E., Rezanezhad, Sh. And Asadpour, Gh., 2021. Evaluation of Strength, Optical and Antibacterial Properties of Treated Papers by Chitosan and Nano Zinc Oxide. Iranian Journal of Wood and Paper Industries, 12: 145-162, (In Persian).
[12] ISO 15105-1:2007, Plastics - Film and sheeting - Determination of gas-transmission rate - Part 1: Differential-pressure methods.
[13] ISO 2528:2017, Sheet materials - Determination of water vapour transmission rate (WVTR) - Gravimetric (dish) method.
[14] ISO 5636-5:2013, Paper and board - Determination of air permeance (medium range) - Part 5: Gurley method.
[15]  ASTM D882-18, Standard Test Method for Tensile Properties of Thin Plastic Sheeting.
[16]  ISO 2758:2014, Paper - Determination of bursting strength.
[17]  Li, X. H., Xing, W. L. Jiang, Y. H. and Ding, Y. L., 2010. Antibacterial and physical properties of poly (vinyl  chloride)-based film coated with ZnO nanoparticles. Food Science and Technology International. 16: 225.
[18]  Zeppa, C., Gouanve, F. and Espuche, E., 2009. Effect of a plasticizer on the structure of biodegradable starch clay nanocomposites: thermal, water sorption, and oxygen barrier properties. Journal of Applied Polymer Science. 112: 2044-2056.
[19] Voon, H. C.,  Bhat, R., Easa, A. M., Liong, M. T. and Karim, A. A., 2012. Effect of addition of halloysite nanoclay and SiO2 nanoparticles on barrier and mechanical properties of bovine gelatin films. Food Bioprocess Technology. 5: 1766 - 1774.