Production of dissolving pulp from populus deltoides wood utilizing alkaline pre-extraction followed by soda-AQ pulping process

Document Type : Research Paper

Authors

1 M.Sc. graguate, Pulp and paper industries, Gorgan university of agricultural sciences and natural resources, Golestan, Iran

2 Associate Prof., Pulp and paper industries, Gorgan university of agricultural sciences and natural resources, Golestan, Iran

3 Professor, Pulp and paper industries, Sari university of agricultural sciences and natural resources, Mazandran, Iran

4 Associate Prof., Department of chemistry, University of Tehran, Tehran, Iran

Abstract

Dissolving pulp is used as a raw material to produce numerous cellulosic derivatives like carboxymethyl cellulose, nitrocellulose, viscose, etc. The potential of dissolving pulp production from populus deltoides using alkaline pre-extraction followed by soda-AQ pulping process was investigated across this research. The yield loss of about 15% was achieved in pre-extraction stage through controlling the process parameters, and kappa number of the pulp has been reduced to about 40% with oxygen delignification. The results showed that the alkaline pre-hydrolysis has been affected on increasing the lignin removal rate of fibers. Using alkali catalyst in pre-hydrolysis liquor led to increasing a-cellulose and decreasing brightness level of the dissolving pulp. The a-cellulose and brightness level of dissolving pulp have been upgraded by utilizing higher levels of kappa factor in D0ED1 bleaching. Therefore, the produced dissolving pulp employing 0.45 kappa factor in D0 stage due to its higher a-cellulose, brightness and purity has been more favorable in this research work.

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Main Subjects


[1] Mahdavi, S., Kermanian, H., Rameani, O. and Molavi, S., 2012. Kraft Pulping of Two Fast Growing Populus euramericana Clones.Journal of Forest and Wood Products. Iranian Journal of Natural Resources, 65(1): 107-118. (In Persian).
[2] Al-Dajani, W.W. and Tschirner, U.W., 2008. Preextraction of hemicelluloses and subsequent kraft pulping, Part 1: alkaline extraction. TAPPI journal, 7(6): 3-8.
[3] Kouhia, M., Holmberg, H. and Ahtilha, P., 2015. Microalgae-utilizing biorefinery concept for pulp and paper industry: Converting secondary streams into value-added products. Algal Research, 10: 41-47.
[4] Saeed, A., Jahan, M.S., Li, H., Liu, Z., Ni, Y. and van Heiningen, A., 2012. Mass balances of components dissolved in the pre-hydrolysis liquor of kraft-based dissolving pulp production process from Canadian hardwoods. Biomass Bioenergy, 39: 14–19.
[5] Ibarra, D., Kopcke, V. and Ek, M., 2010. Behavior of different monocomponent endoglucanases on the accessibility and reactivity of dissolving-grade pulps for viscose process. Enzyme and Microbial technology, 47: 355-362.
[6] Sixta, H., Iakovlev, M., Testova, L., Roselli, A., Hummel, M., Borrega, M., Van Heiningen, A., Froschauer, C. and Schottenberger, H., 2013. Novel concepts of dissolving pulp production. Cellulose, Springer, 20: 1547-1561.
[7] Mehdikhani, H., Jalali Torshizi, H., Jafari Petroudy, R. and Mirshokraei, A., 2016. Carboxymethyl cellulose (CMC) preparation from mixed office wastepaper deinked and bleached bagasse pulps: characterization and comparison.  Iranian Journal of Wood and Paper Industries, 7(3): 311-321. (In Persian).
[8] Feyzmand, M., Resalati, H., Kermanian, H., Jalali Torshizi, H. and Ramezani, O., 2012. Wheat Straw Pre-Extraction with Hot Water and the Recovered Pulping Liquor and Its Effects on Pulping and Paper Properties. Iranian Journal of Chemistry & Chemical Engineering (IJCCE), 31(3): 71-78. (In Persian).
[9] Schild, G. and Sixta, H., 2011. Sulfur-free dissolving pulps and their application for viscose and lyocell. Springer, Cellulose, 18: 1113-1128.
[10] Hasanjanzadeh, H., Hedjazi, S. and Jamalirad, L., 2014. Investigation on the Influence of the Alkaline Preextraction of Hemicelluloses on the Properties of Rice Straw Soda-AQ Pulp. Journal of Forest and wood product, 66(4): 493-506. (In Persian).
[11] Resalati, H., Asadollahzadeh, M.T. and Ghasemian, A., 2011. The effect of acid catalysis in Hot Water Pre-extraction on Soda-AQ pulping from Kenaf Stem. Wood & Forest Science and Technology,18(3): 107-126. (In Persian).
[12] Zhang, H. and Yung, R.A., 2011. Effect of hot water pre-extraction on alkaline pulping and properties of wheat straw. Advance Material Research, 236-238: 1174-1177.
[13] Li, G., Fu, S., Zhou, A. and Zhan, H., 2015. Improved cellulose yield in the production of dissolving pulp from Bamboo using acetic acid in prehydrolysis. BioResources, 10(1): 877-886.
[14] Hoseinkhani, S., Resalati, H., Saraeian, A.R. and Dehghani, M.R., 2012. Effect of pre- extraction liquid reuse on and soda-AQ pulp properties made up of wheat straw. Iranian Journal of Wood and Paper Industries, 4(1): 1-12. (In Persian).
[15] Garmaroody, E., Foolladi, H., Jalili Torshizi, H. and Chaharmahali, A., 2015. Comparative study on pulping conditions of cotton linters produced in four different countries for alpha-cellulose pulp production. Iranian Journal of Wood and Paper Science Research, 30(4): 618-631. (In Persian).
[16] Nikkhah, M. and Resalati, H., 2015. The potential of acid pre-hydrolyzed Soda-AQ process to manufacture highly purified α-cellulose.Iranian Journal of Wood and Paper Science Research, 30(1): 269-279. (In Persian).
[17] Yuan, Z., Wen, Y., Sella Kapu, N., Beatson, R. and Martinez, D.M., 2017. A biorefinery scheme to fractionate bamboo into high-grade dissolving pulp and ethanol. Biotechnol Biofuels, 10:38. 1-17.
[18] Asadpour Attoeii, Gh., Alipour M., Zabihzadeh S.M. and Ghazvini, Z., 2016. Effects of hot water and alkali Pretreatment on yield and optical and resistance properties of Hornbeam CMP pulp. Wood & Forest Science and Technology,23(3): 199-220. (In Persian).
[19] Behin, J., Mikaniki, F. and Fadaei, Z., 2008. Dissolving pulp (alpha-cellulose) from corn stalk by kraft process. Iranian Journal of Chemical Engineering, IAChE 5(3): 14-28. (In Persian).
[20] Alfaro, A., Rivera, A., Perez, A., Yanez, R., Garcıa, J.C. and Lopez, F., 2009. Integral vaporization of two legumes by autohydrolysis and organosolv delignification. Bioresource Technology, 100(1): 440-445.
[21] Garrote, G., Dominguez, H. and Parajo, J.C., 2001. Kinetic modelling of corncob autohydrolysis. Process Biochemistry, 36. 571-578.
[22] Alén, R., Basic chemistry of wood delignification, In: Stenius, P. (Ed.). 2000. Forest Products Chemistry. Papermaking Science and Technology Series, Fapet Oy, Helsinki, 59–104.
[23] Samuelson, O., 1994. Optimized oxygen bleaching of kraft pulp threated with nitrogen dioxide. Tappi Journal, 77: 127-133.
[24] Sjogren, B. and Hook, J., 2000. Extended oxygen delignification- The effect of pretreatments and process conditions, International Pulp Bleaching Conference, Halifax, Canada, p 89-96.
[25] Azadfar, M.A., Behrooz, R. and Jahan-Latibari, A., 2011. The influence of alkalinity in oxygen delignification of Soda/AQ pulp from old corrugated container. Iranian Journal of Wood and Paper Science Research, 26(2): 232-242. (In Persian).
[26] Bouiri, B. and Amrani, M., 2009. Production of dissolving grade pulp from Alfa. BioResources, 5(1): 291-302.
[27] Sarwar Jahan, M., Ahsan, L., Noori, A. and Quayyum, M.A., 2008. Process for the production of dissolving pulp from Trema orientalis (Nalita) by prehydrolysis kraft and soda-ethylenediamine (EDA) process. BioResources, 3(3): 816-826.
[28] Nikkhah Dafchahi, M. and Resalati, H., 2012. Evaluation of Pre-Hydrolyzed Soda-AQ Dissolving Pulp from Populus Deltoides Using av ODED Bleaching Sequence. BioResources, 7(3): 3283-3292.
[29] Kircl, H. and Akgul, M., 2002. Production of dissolving grade pulp from poplar wood by ethanol-water process. Turk Journal of Agriculture, 26: 239-245.