The effect of nanoclay particles and compatibilization of oxidized polypropylene in molten phase on the mechanical and physical properties of wood-plastic composite

Document Type : Research Paper

Authors

1 Assistant Prof., Department of wood and paper science and technology, Faculty of natural resources, University of Zabol, Zabol, Iran

2 M.Sc. Graduated, Department of Wood and Paper Science and Technology, Faculty of Natural Resources, University of Zabol, Zabol, Iran

3 Lecturer, Department of wood and paper science and technology, Faculty of natural resources, University of Zabol, Zabol, Iran

4 Professor, Department of chemical, Faculty of chemical, Amirkabir university, Tehran, Iran

Abstract

The purpose of the research is to examine the effect of nanoclay particles and compatibilization of oxidized polypropylene in molten phase on the mechanical and physical properties of wood-plastic composite made from polypropylene and phragmites ausralis flour. For this purpose, polypropylene in molten phase was oxidized in the vicinity of air oxygen and 1-dodecanol alcohol for 2 hours. Then Phragmites ausralis flour with the weight ratio 50% and the polymer phase was mixed with the compatibilizer at two levels (0 and 3%) and nanoclay particles at three levels (0,2, 4%) in an internal mixer for 6 min under the temperature 165 . Finally, the test specimens were prepared by using the hot press with the dimensions 150×150×2 mm. The mechanical and physical properties including tensile and flexural modulus and strengths, Non-izod impact strength, long term water absorption and thickness swelling were examined according to ASTM standards. The results showed that the using oxidized polypropylene as compatibilizer improves all physical and mechanical properties of the composite. They also showed that increasing nanoclay particles, the physical and mechanical properties of the wood-plastic composite improve, except the Non-izod impact strength. The structural studies of composite and the way the nanoparticles are distributed using x-ray diffraction spectroscopy and SEM images showed that the distribution of nanoclay particles in polymer matrix is of the type of intercalated structures.

Keywords


[1] Madhoushi, M., Dahmardeh New Castle, CE. and Vtbrsa, d., 2008. Internal Bond Strength, Thickness Swelling and Water Absorption in Wood, 3-Layer Made of a Mixture of Straw (Surface layer) and Commercial Types (middle layer). First National Conference of Raw Materials and the Development of the Country's Wood and Paper industry. December 13-12. Gorgan University of Agriculture and Natural Resources. (In Persian).  
[2] Lu, J.Z., Wu, Q. and Negulescu, I., 2005. Wood-Fiber/High-Density-Polyethylene Composites: Coupling Agent Performance. Journal of Applied Polymer Science, 96(1): 93–102.
[3] Fu, J., Naguib, H.E., 2006. Effect of Nano clay on the Mechanical Properties of PMMA/Clay Nano composites Foams, Journal of Cellular Plastic, 42(4): 325-342.
[4] Shokrieh, M. and Sonbolestan, A., 2007. Effects of Structural Parameters on Mechanical Properties Polymer/Clay Nano composites. Journal of Polymer Science and Technology, 20(2): 187-195.
[5] Abdouss, M., SHarifi-Sanjani, N. and Bataille, P., 1999. Oxidation of Polypropylene in a Solution of Monochlorobenzene. Journal of Applied Polymer Science, 47 (14): 3417-3427
[6] Carlsson, D.J., Brousseau, R. and Wiles, D.M., 1986. Reaction of Sulfur Dioxide with Oxidized Polyolefin. Journal of Polymer Degradation and Stability, 15(1): 67-79.
[7] Shlyapnikov, Y., Mar’in, A. and Eur, A.P., 1987. New Phenomena Observed on Dissolution of Low- Molecular Compounds in Polymers: Antioxidant Solubility. Journal of Polymer, 23(8): 629-632.
[8] Kazemi Najafi, S., Bahra, A. and Abdouss, M., 2010. Effect­ of Oxidized Polypropylene as a New Compatibilizer on Water Absorption and Mechanical Properties of Wood Flour/Polypropylene Composites. Journal of Applied Polymer Science, 119(1): 438-432.
[9]  Adhikary, K.B., Pang, S. and Staiger, M.P., 2008. Long-term Moisture Absorption and Thickness Swelling Behavior of Recycled Thermoplastics Reinforced with Pinus radiata sawdust. Journal of Chemical Engineering, 142 (2): 190-198.
[10]  Xue, Y., Veazie, D., Glinsey, C., Wright, M. and Rowell, R.W., 2003. Mechanical and Physical Properties of Wood Fiber Composite under the Influence of Temperature. The 7 International Conference on Wood Fiber- Plastic Composites and other Natural Fiber. May 19-20, Madison, Wisconsin, USA: 339-343.
[11]  Broysiak, S., Paukszta, D. and Helwig, M., 2006. Flammability of Wood-Polypropylene Nano composites. Polymer Degradation and Stability, 91(12): 3339-3343.
[12]  Han, G., Lei, Y., Wu, Q., Kojima, Y. and Suzuki, S., 2008. Bamboo-Fiber Filled High Density Polyethylene Composites; Effect of Coupling Treatment and Nano-clay. Journal of Polymer and the Environment, 16 (2): 123-130.
[13]  Reisi Nafchi, H., Abdouss, M., Kazemi Najafi, S., Mohebbi gargari, R. and Mazhar, M., 2015. Effects of Nano-clay Particles and Oxidized Polypropylene Polymers on Improvement of the Practical Properties of Wood-Polypropylene Composite. Advanced Composite Materials, 24(3): 239-248.
[14] Wang, H., Zheng, C., Elkovitch, M., Lee, J. and Koelling, K.W., 2001. Processing and Properties of Polymeric Nano composites. Journal of polymer Engineering Science, 41(11), 246-246.
[15] Wang, L.; Wang, K.; Chen, L.; Zhang, Y., He, C., 2006. Preparation, Morphology and Thermal/Mechanical Properties of Epoxy/ Nano-clay Composite. Composites Part A: Applied Science and Manufacturing, 37(11): 1890-1896.
[16] Wu, Q., Lei, Y., Clemons, C.M., Yao, F., Xu, y. and Lian, K., 2007. Proportions of HDPE/Clay/Wood Nano composites. Journal of Plastic Technology, 27(2), 108-115.
[17] Karimzadeh, F., Ghasemali, OR. and Salemzadeh, SA., 2005. Nano-materials, Properties, Production and Application. Scientific Jihad Center of Esfahan University. 169 Pp. (In Persian).
[18] Reddy, C.R., Sardashti, A.P. and Simon, L.C., 2010. Preparation and Characterization of Polypropylene–Wheat Straw–Clay Composites. Composites Science and Technology, 70(12): 1674-1680.
[19] Kord, B., Ekrami, M. and Roohani, M., 2014. Effect of Nano-clay Particles Content on the Mechanical Properties of Wood Flour-Polypropylene Composites Using Dynamic Mechanic Thermal Analysis. Iranian Journal of Wood and Paper Industries, 5(2):15-26.
[20] Haghpanah, M., Nosrati Sheshkal, B., Farrokhpayam, S.R. and Mohebbi Gargari, R., 2015. The Effect of Using the Textile Waste Fibers and Nano-Clay Particles on Physical and Mechanical Properties of Composite Made from Wood Flour/Polypropylene. Iranian Journal of Wood and Paper Industries, 6(1):15-26.
[21] Deshmane, C., Yuan, Q. and Misra, R.D.K., 2007. High Strength-Toughness Combination of Melt Intercalated Nano-Clay Reinforced Thermoplastic Olefins. Journal of Material Science Engineering: A, 460-461(7): 277-287.
[22]  Sain, M., Suhara, P., law, S. and Bloullooux, A., 2005. Interface Modification and Mechanical Properties of Natural Fiber-Polyolefin Composite Products. Journal of Reinforced Plastics and Composites, 24(2): 121-130.
[23] Zahedi, M. and Tabarsa, T., 2014. Physico-Mechanical and Morphological Properties of Nano Composite Made from Canola Stalk. Iranian Journal of Wood and Paper Science Research, 28(4): 742-754. (In Persian).
[24] Zaheddi, M., Tabarsa, T., Madhoushi, M. and Shakeri, A.R., 2013. Effect of Nano-clay (Montmorillonite) on the Physical-Mechanical Properties of Polypropylene/Wood Flour Composites. Journal of Wood & Forest Science and Technology, 20(3): 96-110.
[25] Kraby, M., Ghasemi, A. and Mohammadi, M., 2007. Optimization and Use of Nano Fillers in Plastic Compounds. Final Report of the Research Committee of the Ministry of Science and Nanotechnology, Iran Polymer and Petrochemical Institute, Iran, 191p.
[26] Liu, W., Hoa, S.V. and Pugh, M., 2005. Fracture Toughness and Water Uptake of High-Performance Epoxy/Nano Clay Nano Composites. Journal of Composites Science and Technology, 65(15-16): 2364-2373.
[27] Ziaei Tabari, H., Nourbakhsh, A. and Ashore, A., 2011. Effects of Nano Clay and Coupling Agent on the Physico-Mechanical, Morphological, and Thermal Properties of Wood Flour/Polypropylene Composites. Journal of Polymer Engineering & Science, 51(2): 272-277.
[28] Kord, B., 2009. Improvement of Practical Properties of Wood Polymer Composite with Nano clay Particles.  Journal of Engineering Materials, 1(4): 375-383.
Wang, L., Chen, L., Zhang, Y. and He, C., 2005. Preparation, Morphology and Thermal/Mechanical Properties of Epoxy/Nano clay Composite. Composites Part A: Applied Science and Manufacturing, 37(11): 1890-1896