Investigation of ِDecay Resistance of Poplar Plywood with Encapsulated Pesticides

Document Type : Research Paper

Authors

1 MSc. Department of wood and paper science and technology, Faculty of natural resources, University of Zabol, Zabol, Iran

2 Department of wood and paper science

3 Academic Staff Member at University of Zabol.

4 Associate Professor Faculty of Natural Resources and Earth Sciences, Shahrekord University

Abstract

Borons and copper-based compounds are compounds used as pesticides and fungicides. One of the main problems of these compounds is that they easily be washed. Therefore, the main purpose of this study is to stabilize and reduce the leaching of protective materials using the encapsulation method. The encapsulation method of pesticides (boric acid and Bordeaux) was performed by natural chitosan polymer via electrospinning method and the compounds were used to treat poplar wood layers and make plywood. To evaluate the performance of the final product, physical tests (density, thickness swelling and water absorption), Fourier transform infrared spectroscopy and fungal tests were performed. The results showed that despite the low load of boric acid and pesticide, the performance of the layers was effective against fungal degradation. However, after severe leaching, their performance was reduced. The layers treated with the encapsulated pesticides retain their function as a pesticide against the fungus after washing. In general, the results showed that the technique of encapsulating pesticides can significantly reduce their leaching and on the other hand leads to maintain the function of pesticides.

Keywords


[1] Xie, L., Tang, Z., Jiang, L., Breedveld, V., & Hess, D. W., 2015. Creation of superhydrophobic wood surfaces by plasma etching and thin-film deposition. Surface and coatings technology, 281, 125-132.
[2] Himmel, S., & Mai, C., 2016. Water vapour sorption of wood modified by acetylation and formalisation–analysed by a sorption kinetics model and thermodynamic considerations. Holzforschung, 70(3), 203-213.
[3] Köhler, R., Sauerbier, P., Ohms, G., Viöl, W., & Militz, H., 2019. Wood protection through plasma powder deposition-An alternative coating process. Forests, 10(10), 898.
[4] Bahmani, M., & Schmidt, O. 2018. Plant essential oils for environment-friendly protection of wood objects against fungi. Maderas. Ciencia y tecnología, 20(3), 325-332.
[5] Bahmani, M., Schmidt, O., Fathi, L., & Frühwald, A. 2016. Environment-friendly short-term protection of palm wood against mould and rot fungi. Wood Material Science & Engineering, 11(4), 239-247.
[6] Chu, Demiao, Redžo Hasanagić, Atif Hodžić, Davor Kržišnik, Damir Hodžić, Mohsen Bahmani, Marko Petrič, and Miha Humar. 2022. Application of Temperature and Process Duration as a Method for Predicting the Mechanical Properties of Thermally Modified Timber. Forests, 13(2), 217.
[4] Zanini, S., Riccardi, C., Orlandi, M., Fornara, V., Colombini, M. P., Donato, D. I., ... & Palleschi, V., 2008. Wood coated with plasma-polymer for water repellence. Wood Science and Technology, 42(2), 149-160.
[5] Doosthoseini, K., Ghorbani, K. M., Mohamadalibeik, S., & Karimi, A. N., 2011. Investigation on the effect of acetylation and the resin type on the biological resistance of aspen tree layered particleboard. Iranian Journal of Wood and Paper Science Research, 26(3), 466-476.
 [6] Zabel, R. A. and Morrell, J. J., 2012. Wood microbiology: decay and its prevention. Academic press.
[7] Sobhani Oskooi, F., Ghorbani, M. and Amini Nasab, S., 2017. Mechanical behavior and biological resistance of wood-acrylonitrile polymer modified with alkoxysilane. Wood and Forest Science and Technology Research, 24(1): 103-116. (In Persian)
[8] Sotsek, N. C., & Santos, A. D. P. L., 2018. Panorama do sistema construtivo light wood frame no Brasil. Ambiente construído, 18, 309-326.
[9] Tufolo Netto, H., 2010. Benefícios do uso da madeira de reflorestamento tratada para a construção civil. 2010. 47 p. Monografia (Especialização em Gestão Empresarial)–Instituto Nacional de Pós Graduação, São Paulo.
[10] Dos Santos, H. S., Ferrarini, S. F., Flores, F. Q., Pires, M. J., Azevedo, C., Coudert, L., & Blais, J. F., 2018. Removal of toxic elements from wastewater generated in the decontamination of CCA-treated Eucalyptus sp. and Pinus canadense wood. Journal of Material Cycles and Waste Management, 20(2), 1299-1309.
[11] Efhami Sisi, D. and Hamzeh. Y., 2017. Borates and their application in the protection of wooden composites. Iranian Journal of Wood and Paper Industries, 9 (3): 411-428. (In Persian)
[12] Freeman, M. H., Mcintyre, C. R. and Jackson, D., 2009. A critical and comprehensive review of boron in wood preservation. In proceedings of the American Wood Protection Assoc, 105: 279–294.
[13] Clausen, C., 2012. Enhancing durability of wood-based composites with nanotechnology. USDA Forest Service, Forest Products Laboratory, General Technical Report, FPL-GTR-218: 8-12.
[14] Pizzi, A. and Baecker, A., 1996. A new boron fixation mechanism for environment friendly wood preservatives. Holzforschung, 50(6): 507–510.
 [15] Bhatt, S. and Tripathi, S., 2021. Effect of silicic acid on boron leaching in plywood manufacture.
[16] Jämsä, S., Mahlberg, R., Holopainen, U., Ropponen, J., Savolainen, A. and Ritschkoff, A. C., 2013. Slow release of a biocidal agent from polymeric microcapsules for preventing biodeterioration. Progress in Organic Coatings, 76(1): 269-276.
[17] Ganne-Chédeville, C., Jääskeläinen, A. S., Froidevaux, J., Hughes, M., and Navi, P., 2012. Natural and artificial ageing of spruce wood as observed by FTIR-ATR and UVRR spectroscopy. Holzforschung, 66(2): 163-170.‏
[18] Yildiz, S., Yildiz, U. C. and Tomak, E. D., 2011. The effects of natural weathering on the properties of heat-treated alder wood. BioResources, 6(3): 2504-2521.‏
[19] Asghari, S. M., Ebrahimi Samani, S., Siraj, Z., Khajeh, Kh. and Hosseinkhani. S.,2013. Optimization of chitosan nanoparticle synthesis. Biotechnology of Tarbiat Modares University 4(2): 29-21. (In Persian)
[20] Smith, W. R. and Wu, Q., 2005. Durability improvement for structural wood composites through chemical treatments current state of the art. Forest Products Journal, 55(2): 8–17.
[21] Lebow, S. T., 2010. Wood Handbook, Chapter 15: Wood preservation. General Technical Report FPL-GTR-190. Madison, WI: U.S. Department of Agriculture, Forest Service, Forest Products Laboratory, 43p.