Effect of Bene gum on the physical and mechanical properties of oil-heat treated wood

Document Type : Research Paper

Authors

1 Ph.D. student, Department of wood and paper science & technology, Faculty of natural resources, University of Tehran, Karaj, Iran

2 Associate Prof., Department of wood and paper science & technology, Faculty of natural resources, University of Tehran, Karaj, Iran

3 Professor, Department of wood and paper science & technology, Faculty of natural resources, University of Tehran, Karaj, Iran

4 Associate Prof., Department of wood engineering and technology, Gorgan university of agricultural sciences and natural resources, Gorgan, Iran

Abstract

Cooling of oil-heat treated wood which is carried out at the final stage of thermal modification process can affect the properties of the modified wood. In the present study, poplar wood modified in canola oil (at 180, 200 and 220°C for 2 h) was cooled in the cold oil containing 0, 5 and 10% Bene gum (Pistacia atlantica) for 30 minutes. The weight gain percentage (WPG) of specimens ranged from 60.7 to 77.6 % and reduced by increasing in the modification temperature; however, the WPG increased as a result of cooling in the oil containing Bene gum. On the whole, cooling in in the oil containing Bene gum had no significant effect on the moisture exclusion and anti-swelling efficiencies whereas improved the water repellent efficiency. The results of dynamic contact angle measurement for 60 s also showed that cooling in the oil with Bene gum reduced more the wettability of the modified wood. Increasing the gum content from 5 to 10% had no significant effect on this property. As a result of adding the Bene gum in oil, the bending strength and compression strength parallel to grain were not changed but the impact resistance of the wood specimens modified at 180°C and modulus of elasticity of those modified at 220°C were improved. The results of ATR-FTIR showed that the peak intensity at wavenumber of 1745 cm-1 which is related to the stretching vibration of carbonyl group (C=O) was higher in the modified wood compared to the untreated wood probably due to the presence of oil in the modified wood.

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[1] Hill, C. A. S., 2006. Wood Modification – Chemical, Thermal and Other Processes, C. Stevens (ed.), John Wiley & Sons Ltd., Chichester.
[2] Sailer, M, Rapp, A.O. and  Leithoff, H ., 2000. Improved resistance of Scots pine and spruce by application of an oil-heat treatment. The International Research Group on Wood Preservation IRG/WP 00-40162.
[3] Rapp, A.O. and Sailer, M., 2001. Oil heat treatment of wood in Germany-State of the art. In: Review on heat treatments of wood. COST Action E22, Environmental optimisation of wood protection. Proceedings of the special seminar held in Antibes, Forestry and Forestry Products, France, 66p.
[4] Wang, J., 2007. Initiating evaluation of thermal-oil treatment for post-MPB lodgepole pine. Forintek Canada Corp., Vancouver BC, Canada.
[5] Tomak, E. D., Hughes, M., Yildiz, U.C. and Viitanen, h., 2011. The combined effects of boron and oil heat treatment on beech and Scots pine wood properties. Part 1: Boron leaching, thermogravimetric analysis, and chemical composition. Journal of Materials Science, 46:598–607.
[6] Tarmian, A., 2017. Measurement of Fiber Saturation Point of Wood Using Differential Scanning Calorimetry: Measurement Fundamentals and Experimental Results. Iranian Journal of wood and paper industries, 7(4):615-623. (In Persian).
[7] Mohebby, B., Kevily, H. and Kazemi-Najafi, S., 2014. Oleothermal modification of fir wood with a combination of soybean oil and maleic anhydride and its effects on physico-mechanical properties of treated wood. Wood Science Technology, 48:797–809.
[8] Pourreza, M., Shaw, J.D. and  Zangeneh, H., 2008. Sustainability of wild pistachio (Pistacia atlantica Desf.) in Zagros forests, Iran. Forest Ecology and Management. 255: 3667–3671.
[9] Daryaei, M.G., Hoseiny, S.K., Taheri, K., Mirzaei, J. and Mzbani, A., 2012. Effect of morphological variables of Pistacia atlantica on gum and seed production. Iranian Journal of Biology, 25(2): 303-315. (In Persian).
[10] Awoyemi, L., Cooper, P.A. and Ung, T.Y., 2009.  In-treatment cooling during thermal modification of wood in soy oil medium: soy oil uptake, wettability, water uptake and swelling properties. European Journal of Wood and Wood Products, 67: 465–470.
 [11] Baker, B. and  Owen, N.L., 1999. Identifying softwoods and hardwoods by infrared spectroscopy. Journal of Chemical Education, 76: 1706-1709.
[12] Bazyar, B., 2012. Aspen decay & oil heat treatment. Bio-Resources, 7(1): 696-705.
[13] Grenier, D.,Bailleres, H., Meot, J.M., Langbour, P. and Lanvin, J.D., 2003. Oil absorption during oleothermic treatment of wood. In: The First Europen Conference on Wood Modification ECWM 2003, Ghent, Belgium.
[14] Dubey, M.K., Pang, S. and Walker, J., 2012. Changes in chemistry, color, dimensional stability and fungal resistance of Pinus radiate D. Don wood with oil heat-treatment. Holzforschung, 66(1): 49-57.
[15] Pétrissans, M., Gerardin, P. and Serraj, M., 2003. Wettability of heat-treated wood. Holzforschung, 57(3): 301-307.
[16] Hakkou, M., Petrissans, M., Zoulalin, A. and Gerardin, P., 2005. Investigation of wood wettability changes during heat treatment on the basis of chemical analysis. Polymer Degradation and Stability, 89: 1-5.
[17] Esteves, B.M. and Pereira, H.M., 2009. Wood modification by heat treatment: a review. Bioresources, 4:370–404.
[18] Boonstra, MJ., Van Acker, J., Tjeerdsma, B.F. and  Kegel, E.V., 2007. Strength properties of thermally modified softwoods and its relation to polymeric structural wood constituents. Annals of forest science, 64:679–690.