Effect furfurylation on physical properties and surface quality of two species of Beech and Fir

Document Type : Research Paper

Authors

1 Assistant Professor, Wood science & Technology Department, Civil Engineering Faculty, Shahid Rajaee Teacher Training University, Tehran, Iran

2 M.Sc. Student, Wood science & Technology Department, Civil Engineering Faculty, Shahid Rajaee Teacher Training University, Tehran, Iran

3 PhD., Wood science & Technology Department, Natural Resources Faculty, University of Tehran, Karaj, Iran

Abstract

The objective of this study was investigation of furfurylation effect on water absorption, thickness swelling, contact angle and surface roughness in two species such as beech (Fagus orientalis) and fir (Abies alba). In this regard, two different values of furfurylation of beech and fir wood specimens in the form of low level and high level were carried out and compared with control specimens. The furfurylation was carried out with impregnation under pressure and polymerization of furfuryl alcohol monomer with heat catalyst. For evaluating the water absorption and thickness swelling, specimens were subjected to long-term water immersion, and their dimension changes were determined at different times. The surface roughness and contact angle testes were also carried out. Results indicated that water absorption and thickness swelling were reduced. Results also indicated that drop contact angles were decreased and surface roughness were increased by increasing of furfurylation level.

Keywords


[1] Baysal, E., Ozaki, S.K. and Yalinkilik, M.K., 2004. Dimensional stabilization of wood treated with furfuryl alcohol catalysed by borates. Wood Science and Technology, 38:405-415.
[2] Omidvar, A., 2009. Wood Polymer Composite. Gorgan University of Agricultural Science and Natural Resources Press, Gorgan, Iran, 127.(In Persian).
[3] Revzvani, R., 2010. The effect of furfurylation on physical & mechanical properties of Poplar wood, in Forestry and wood Technology., Gorgan University of Agricultural Sciences and Natural Resources, Gorgan. (In Persian).
[4] Goldstein, I.S., 1955. The impregnation of wood to impart resistance to alkali and acid. Forest Product Journal, 5(4):265-267.
[5] Goldstein, I.S. and Dreher W.A., 1960. Stable furfuryl alcohol impregnation solutions. Industrial & Engineering Chemistry Research, 52(1):57-58.
[6] Lande, S., Westin, M. and Schneider, M., 2004. Properties of furfurylated wood. Scandinavian Journal of Forest Research, 19(Suppl 5):22-30.
[7] Schneider, M.H., 1995. New cell wall and cell lumen wood polymer composites. Wood Science and Technology, 29:121-127.
[8] Esteves, B., Nunes, L. and Pereira, H., 2011. Properties of furfurylated wood (Pinus pinaster). European Journal of Wood and Wood Products, 69:521-525.
[9] Epmeier, H., Johansson, M., Kliger, R. and Westin, M., 2007. Bending creep performance of modified timber. Holz als Roh-und Werkstoff, 65:343-351.
[10] Treu, A., Lückers, J. and Militz, H., 2009. Screening of modified linseed oils on their applicability in wood protection. In: Proceedings of 35th Annual Meetingof the International Research Group on Wood Protection. Ljubljana, Slovenia. IRG/WP, p 30304-30346.
[11] Lande, S., Riel, S., Hoibo, O.A. and Schneider, M.H., 2010. Development of chemometric models based on near infrared spectroscopy and thermogravimetric analysis for predicting the treatment level of furfurylated Scots pine. Wood Science and Technology, 44:189-203.
[12] Abdolzadeh, H., Ebrahimi, G., Layeghi, M., Ghassemieh, M. and Mirshokraie, S.A., 2013. Mechanical properties of Beech -Furfuryl alcohol wood polymer. Iranian Journal of Wood and Paper Industries, 4(2):143-155. (In Persian).
[13] Taghizade Moftikolayi, F., Masteri Farahani, M.R. and Khazayian, A., 2010. Surface Roughness of Linear Chain Carboxylic Acid Anhydride Modified Wood. Iranian Journal of Wood & Forest Science, 17(2):143-155. (In Persian).
[14] Ayrilimis, N., 2005. Variations in compression strength and surface roughness of heat-treated Turkish rirred gum (Eucalyptus Camaldulensis) wood. Science links Japan, 4:405- 409.
[15] Thygesen, L.G., Barsberg, S. and Venas, T., 2010. The fluorescence characteristics of furfurylated wood studied by fluorescence spectroscopy and confocal laser scanning microscopy. Wood Science and Technology, 44:51-65.
[16] Hadi Gholamiyan, H., Tarmian, A., Doost Hosseini, K. and Azadfallah, M., 2011. The effect of clear paints, nanozycofil and nanozycosil on water absorption and contact angle of poplar wood. Iranian Journal of Wood and Paper Industries, 2(1):17-25. (In Persian).
[17] ISO standard, Wood- Determination of moisture content for physical and mechanical tests, 3130, Editor 1975, ISO standard, Switzerland.
[18] Tallaipour, S., 2006. Study of moisture content effect on styrene distribution in Poplar wood polymer composites, In Forestry and wood Technology., Gorgan University of Agricultural Sciences and Natural Resources, Gorgan, p. 102. (In Persian).
[19] Panshin, A.J. and Zeeuw, C.D., 1970. Textbook of Wood Technology: Structure, identification, uses, and properties of the commercial woods of the United States and Canada, McGraw-Hill, the University of Michigan.
[20] Stamm, A.J., 1964. wood and cellulose science., Ronald Press. New York.
[21] Jonoobi, M., Harun, J., Mathew, A.P., Hussein, M.B. and Oksman K., 2010. Preparation of cellulose nanofibers with hydrophobic surface characteristics. Cellulose, 17:299-307.
[22] Ifuku, S., Nogi, M., Abe, K., Handa, K., Nakatsubo, F. and Yano, H., 2007. Surface modification of bacterial cellulose nanofibers for property enhancement of optically transparent composites: Dependence on acetyl-group DS. Biomacromolecules, 8:1973-1978.
[23] Togay, A., Kilic, Y. and Colakoglu, G., 2009. Effect of impregnation with Timbercare Aque to surface roughness of some varnishes. Journal of Appled Science, 9(9):1719-1725.
[24] Buchelt, B., Dietrich, T. and Wagenfuhr, A., 2012. Macroscopic and microscopic monitoring of swelling of beech wood after impregnation with furfuryl alcohol. European Journal of wood and Wood Product, 70(6):865-869.
[25] Abdolzadeh, H., Layeghi, M., Ebrahimi, Gh. and Ghassemieh, M., 2014. Fracture behavior of beech-furan wood/polymer under mode I. Iranian Journal of Wood and Paper Science Research, 29(4):609-622. (In Persian).
[26] Hill, C., 2006. Wood modification: chemical, thermal and other processes. John Wiley and Sons Press.