Investigation on physical behavior of styrene wood-polymer in different concentrations of monomer

Document Type : Research Paper

Authors

1 Associate Professor, Faculty of Natural Resources, Sari Agricultural Sciences and Natural Resources University, Sari, I.R. Iran. (*Corresponding Author)

2 M. Sc. graduated, Department of Wood and paper, Faculty of Natural Resources, Sari Agricultural Sciences and Natural Resources University, Sari, I.R. Iran

Abstract

This research was conducted to study the effect of different concentrations of styrene lumen monomer on the physical properties of beech wood. Physical test samples were prepared according to ASTM-D1037 standard and treated with vacuum-pressure method at five concentration levels; 0, 40, 60, 80 and 100 percent of soluble monomer. For polymerization, treated samples were heated in oven for two 24-hour period at 90 and 103ºC respectively. Monomer and polymer absorption, density variation, water absorption, swelling and anti-swelling efficiency (ASE) were determined. According to the results, Monomer and polymer absorption were increment by monomer concentration increase, and they were reported 38.2% and 26% in highest level. With polymer absorption enhancement, density of wood increased from 0/63g/cm³ in control to 0/91g/cm³ in the highest monomer concentration level that reduces pores in wood-polymer structure. Absorbed polymer enhancement decreased hydrophilicity and dimensional changes of treated samples, so that water absorption and swelling volume of the samples saturated with 100% concentration of monomer were decreased 64% and 45.3% after the longest immersion time. Highest Anti-swelling efficiency of Styrene-saturated samples was determined 56.15% in the maximum concentration level of treatment.

Keywords


[1] Mohebby, B., 2003.Wood and lignocellolusic material modification and their technologies. First national conference of cellolusic material processing and applying.Tehran University, 405-410.
[2] Sjostrom, E., 1993. Wood Chemistry Fundamentals and Applications; Academic Press: San Diego, 293 p.
[3] Abdolmaleki, J. and Omidvar, A., 2003. Evaluation of composite products, WPC prepared using styrene monomer species Populusnigra direct heat method. Journal of Gorgan University of agricultural sciences and natural resources, 9(4): 215-221.
[4] Baysal, E., Yalinkilik, M. K., Altinok, M., Sonmez, A., Peker. H. and Colak, M., 2007. Some physical, biological, mechanical, and fire properties of wood polymer composite (WPC) pretreated with boric acid and borax mixture. Construction and Building Materials, 21: 1879–1885.
[5] Lande, S., Westin, M.  and Schneider, M., 2004. Properties of furfurylated wood. Journal of Forest Research, 19(5): 22-30.
[6] Zaheditajrishi, A. and Omidvar, A., 2007. Resistance of Poplar wood polymer composites against Coriolus versicolor fangus. Journal of Agricultural Science and Natural Resource,14(1): 81-90.
[7] Omidvar, A., 2009. Wood-Polymer Composite. Gorgan University of agricultural sciences and natural resources, Gorgan, 127pp.
[8] Li, Y., Dong, X., Lu, Z., Jia, W. and Liu, Y., 2012. Effect of polymer insitu synthesized from methyl methacrylate and styrene on theorphology, thermal behavior and durability of wood. Journal of Applied Polymer Science, (10):1-8.
[9] Schnieder, M.H., Brebner, K.I. and Hartley, I.D., 1989. Swelling of a cell- lumen filled and wall bulked wood- polymer composite in water. Wood and Fiber Science, 23(2): 165-172.
[10] Kaki, R. and Ghorbani, M., 2013. Investigation on the water absorption and dimensional stability of beech impregnated with methyl methacrylate. Journal of forest and wood products, 6: 329-338.
[11] Lawniczak, V.M., 1994. Method of production of the composite Bamboo polystyrene elaborated in poland. Paper presented on international bamboo festival and national Bamboo convention 1, Bandung, Indonasia.
[12] Devi, R. and Maji, T. K., 2006. Effect of Glycidyl Methacrylate on the Physical Properties of Wood–Polymer Composites. Polymer Composite, 28(1): 1-5.
[13] Li, Y., Liu, Y., Wang, X., Wu, Q., Yu, H. and Li, J., 2011. Wood-Polymer Composites Prepared by In-situ Polymerization of Monomers within Wood. Journal of Applied Polymer Science, 119(6): 3207–3216.
[14] Schnieder, M. H. , 1994. Wood -polymer composites. Wood Fiber Sci, 26(1): 142-151.
 [15] Zhang, Y.L., Wan, H. and Zhang, S.Y., 2005. Characterization of Sugar MapleWood-Polymer Composites: Monomer Retention and Polymer Retention. Holzforschung, 59: 322-329.
 [16] Talaeepour, S. and Omidvare, A., 2008. Investigation of physical properties wood polymer composites from palownia, aspen, maple, hornbeam speiec. Journal of  Pajouhesh and sazandegi, 78: 86-91.
[17] Chao, W.Y. and Lee, A.W., 2003. Properties of Southern pine wood impregnated with styrene. Holzforschung, 57(3): 333-336.
[18] Fruno, T., 1991. The role of wall polymer in the dimensional stability and decay durability of wood-polymer composites (wpc). Proc. Int. Symp. On chemical modification of wood, Kyoto: 160- 165.Japan.