Effect of Hot water and dilute acid pretreatment on the chemical properties of liquorice root

Document Type : Research Paper

Authors

1 MSc. Student, Department of Cellulose and Paper Technology, Shahid Beheshti University, Zirab campus, Savad koh, Mazandaran, Iran.

2 Assistant professor, Department of Cellulose and Paper Technology, Shahid Beheshti University, Zirab campus, Savad koh, Mazandaran, Iran.

3 Associated professor, Department of Wood and Paper Science and Technology , Faculty of Natural Resources, University of Tehran, Karaj, Alborz, Iran.

Abstract

Abstract In this study, the liquorice root (Glycyrrhiza glabra) that was extracted in the factory in Kerman province, pre-hydrolyzed and then chemical compositions (Extractives, Lignin content, Holocellulose percent), the hydrolysis process yield and weight loss of the waste was measured. Pre-hydrolysis process was done on the above mentioned waste by hot water, hot water followed by 0.5 percent sulfuric acid and also alone sulfuric acid with different concentrations (0.5, 1, 1.5 and 2 percent) The samples were pre-hydrolyzed in hot water at 150 °C and 30, 60 and 90 minutes as well as in the mixture of hot water and 0.5 % sulfuric acid at 150 °C and 60 minutes and also in pure sulfuric acid, at 130 °C and at 60 minutes. The results showed that the pre-hydrolyzed treatment with hot water in 60 minutes had been favorable performance in the respect of weight loss, lignin content and holocellulose percent. Also, in the case of pre-treatment including sulfuric acid, 2% dose can be good selected option in term of maximum holocellulose percent and minimum lignin content so that it can be suggested to produce higher value-added products such as bioethanol from licorice root bid.

Keywords


[1] Inoue, S.and Yoshimura, T., 2009. Hydrothermal treatment with phosphoric acid for enzymatic saccharification of rice straw. The 6th Biomass-Asia Workshop, 18-19 November, Hiroshima.
[2] Endo, T., Tanaka, N., Sakai, M., Teramoto, Y. and Lee, S.H., 2006. Enhancement mechanism of enzymatic saccharification of wood by mechanochemical treatment. In: the Third Biomass-Asia Workshop, 11/15-17, Tokyo and Tsukuba, p. 105.
[3] Jatav, V. S. K., Singh, S., Khatri, P. K. and Sharma, A., ­2011. Recent pharmacological trend of Glycyrrhiza glabra linn. International Journal of Pharmaceutical Frontier Research, 1(1): 170- 185.
[4] Bolory,-Moghaddam, E. and Hemmati, KH., 2009. The impact of harvest time and the amount of glycyrrhizin in licorice root diameter. Plant Production of Journal, 16 (2): 29-45.
[5] Ranaey Siyadat, A., Niknam, K. and Barshan Tashnizi, M., 2011. Cellulase key of energy, Industrial Research and Training Centre of Iran, First Edition, Tehran, 679p. (In Persian).
[6] Wood, T. M. and Mccrae, S. i., 1978. The Cellulose of Trichoderma Koningii. Biochemistry Journal, 171: 61-72.
[7] Vijai, K. G. and Maria, G. T., 2013. Biofuel technologies, Springer-Verlog, Berlin Heidelberg, 534p.
[8] Mosier, N., Wyman, C., Dale, B., Elander, R., Lee, Y. Y., Holtzapple, M. and Ladisch, M., 2005. Features of promising technologies for pretreatment of lignocellulosic biomass. Bioresource Technology, 96(6): 673–686.
[9] Taherzade, M. and Karimi, k., 2008. Pretreatment of Lignocellulosic Wastes to Improve Ethanol and Biogass Production. International Journal of Molecular Sciences, 9: 1621- 1651.
[10] Sendelius, J., 2005. Steam Pretreatment optimization for Sugarcane Bagass in bioethanol production, M.Sc. thesis, Lund Institute of technology, Lund University, Sweden.
[11] Li, S., Li, J., Hu, X., Li, M., Yan, Zh., Li, Sh. and Fan, Ch., 2013. Study on enzymatic saccharification of Suaeda salsa as a new potential feedstock for bio-ethanol production. Journal of the Taiwan Institute of chemical Enjineers, 44 (6): 904-910.
[12] Al-dajani., Waleed, W. and Ulrike, W., 2009. Pre-extraction of hemicelluloses and subsequent kraft pulping, Part II: acid and autohydrolysis. TAPPI Journal,8: 30-37.
[13] Guo, G.L., Hsu, D.Ch., Chen, W.H., Chen, W. and Hwang, W.S., 2009. Characterization of enzymatic saccharification for acid-pretreatedlignocellulosic materials with different lignin composition. Enzyme and Microbial Technology, 45: 80–87.
[14] Ahmed, I. A., Santoso, Sh. P., Tran-Nguyen, Ph. L. H., Ismadji, S. and JU, Y., 2013. Impact of pretreatments on morphology and enzymatic saccharification of shedding bark of Melalenca Leucadendron. Bioresource Technology, 139: 410- 414.
[15] Rabbani Esfahani, M., 2010. Compare the types of pretreatment of lignocellulosic biomass to ethanol to natural biological method, 8th Iranian student conference of chemical engineering, technical faculty, Razi University, Kermanshah. (In Persian).
[16] Hossein, M. A., 2011. C Investigation on Properties of Soda and Soda/AQ Pulps from Corn Stalk. Journal of Wood & Forest Science and Technology, 18(2): 57-72. (In Persian).
[17] Teramoto, Y., Tanaka, N., Lee, S.H. and Endo, T., 2008. Pretreatment of Eucalyptus Wood Chips for Enzymatic Saccharification Using Combined Sulfuric Acid-Free Ethanol Cooking and Ball Milling. Biotechnology and Bioengineering, 99: 75-85.
[18] Rasooly Garmaroody, E., 2011. The Effect of Wood Biological Pre-treatment on kraft Pulp and Paper Properties of Hornbeam and Poplar, Ph.D. Thesis, Gorrgan university of Agricultural Sciences and Natural resources. (In Persian).
[19] Fooladi, H., 2011. Optimization of Cotton Linter Pulping for α Cellulose production (case study: Parchin chemical industries Co.), Shahid Beheshti University. (In Persian).
[20] Wang, W., Yuan, T., Cui, B. and Dai, Y., 2013. Investigating lignin and hemicellulose in white rot fungus-pretreated wood that affect enzymatic hydrolysis. Bioresource Technology, 134: 381–385.
[21] Uju Abe, K., Uemura, N., Oshima, T., Goto, M. and Kamiya, N., 2013. Peraceticacid-ionic saccharification of lignocellulosic biomass. Bioresource Technology, 134: 87-94.