Study on Leaching of Copper Nanoparticles in Combined Impregnation- Densification Treatments of wood after Accelerated Aging

Document Type : Research Paper

Authors

1 Assistant professor Academic member /Shahid Rajaee Teacher Training University

2 M.Sc. Graduate Student, Department of Wood Industry Faculty of Civil Engineering, Shahid Rajaee Teacher Training University

3 Research manager, Zelam Limited, 15 Hudson Road, New Plymouth 4341, New Zealand

Abstract

This study was performed to evaluate the leaching rate of copper nanoparticles in combined impregnation-densification treated poplar and spruce wood after accelerated aging. Specimens were prepared by impregnation with 200 and 400 ppm nano-copper suspensions, followed by pre-steam treatment and densification. Impregnation was done in a sealed vessel with 4 bar pressure in 20 minutes. Half of the specimens were oven-dried and steamed at 150°C for 2 hours and immediately densified under the hot press at 170°C for 3 hours to reach to the 33% compression rate. All specimens were exposed to the 6 steps accelerated aging procedure according to ASTM D-1037. Leaching test was performed according to EN84 standard (1997) for a period of 14 days. The leached residues were investigated in the Mineral Exploration and Geological Center by atomic absorption method. Results showed that nano-copper particles in impregnated specimens had no leaching; but the pre-steaming and densification treatments led to leaching the nano-copper particles from the treated wood.

Keywords

Main Subjects


[1]       Rassam, G., Ghofrani, M., Taghiyari, H R., Jamnani, B., Khajeh, M.A., 2012. Mechanical performance and dimensional stability of nano-silver impregnated densified spruce wood. European Journal of Wood and Wood Products, 70: 595–600.
[2]       Taghiyari, H.R., Ghorbani, .M. and Kalantari, A., 2013. Effects of silver and copper nano particles on gas and liquid permeability of heat-treated solid woods. Special Topics & Reviews in Porous Media —An International Journal, 4(1): 81–97.
[3]       Taghiyari, H.R, Enayati, A. and Gholamiyan, H., 2013. Effects of nano-silver impregnation on brittleness, physical and mechanical properties of heat-treated hardwoods. Wood Science and Technology, 47: 467–480.
[4]       Kalbasi, M.R., Abdollahzadeh E., Salari joo H., 2012. Effect of colloidal silver nanoparticlesvon population of gut bacteria flora of rainbow trout. Journal of Veterinary Research, 67(2): 181-189 (In Persian).
[5]       Accelerated ageing of treated wood prior to biological testing - Leaching procedure. BS EN 84: 1997
[6]       Standard Test Methods for Evaluating Properties of Wood-Base Fiber and Particle Panel Materials, ASTM Standard, D-1037, 2012.
[7]       Matsunaga, H., Kiguchi, M. and Evans, P., 2007. Micro-distribution of metals in wood treated with a nano-copper wood preservative. International Research Group on Wood Protection, Document No.  IRG/WP 07-40360. 10 p.
[8]       Mortimer, C.E., 1998. General Chemistry, Wadsworth Publishing Company, 902 p.
[9]       Dashti, H., Tarmian, A., Faezipour, M. and Shahverdi, M., 2011. Effect of pre-steaming on mass transfer properties of fir wood (Abies alba L.): A gymnosperm species with torus margo pit membrane. BioResources, 72: 1907-1918.
[10]   Sayar, M., Tarmian, A., Azadfallah, M. and Taghiyari, H.R., 2013. Thermal treatment and its effect on the gas permeability of Populus nigra. Iranian Journal of Wood and Paper Industries, 4(1): 151-159.  (In Persian).