Evaluation of the Effect of Endoglucanase Refining on the Physical and Mechanical Properties of Paper Made from OCC Pulp

Document Type : Research Paper

Authors

Abstract

In this study, the effect of enzymatic refining with endoglucanase was investigated on the physical and mechanical properties of OCC pulp. Collected OCC pulps were pre-treated with different endoglucanse dosages (1u, 2u and 3u on o.d. pulp) under constant conditions and then refined at different levels. The effect of different enzyme dosages and refining levels were evaluated separately on the paper physical and mechanical of properties, as compared to control pulp (non treated pulp with enzyme). In unrefined pulps, the results have shown that adding enzyme up to 1u caused to improve the physical and mechanical properties as significant (confidence level of 95%), compared to control pulp. However using more than 1u endoglucanase resulted in a significant decrease in both physical and mechanical properties. Achieved results from the effect of different enzyme dosages and refining levels showed that in refined pulps, increase of enzyme level caused to produce a bulky paper and decrease of mechanical properties. In general, the best physical and mechanical properties were obtained using 1u endoglucanase at different refining levels applied.

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[1]     Bajpai, P.K., 2010. Solving the problems of recycled fiber processing with enzymes.Journal of Bioresources, 5(2):1-15.
[2]     Verma, P., and Bhardwaj, N.K., and Chakraborti, S.K., 2010. Enzymatic upgradation of secondary fibers. Journal of Ippta, 22(4):133-136.
[3]     Pala, H., Lemos, M.A., Mota, M., and Gama, F.M. 2001. Enzymatic upgrade of old paperboard containers. Journal of Enzyme and Microbial Technology, 29:274-279.
[4]     Pala, H., Mota, M., and Gama, F.M., 2002. Refining and enzymatic treatment of secondary fibers for paperboard production: cyberflex measurement of fiber flexibility. Cost E20-Wood Fiber Cell Wall Structure.
[5]     Dienes, D., Egyházi, A., and Réczey, K. 2004. Treatment of Recycled Fiber with Trichoderma Cellulases. Journal of Industrial Crops and Products. (20):11–21.
[6]     Tripathi, S., Nirmal, Sh., Mishra, O., Bajpai, P., and Bajpai, P.K. 2008. Enzymatic Refining of Chemical Pulp. Journal of Ippta. 20(3):129-132.
[7]     Wu, Q., Chen, J., Yang, G., Wang, Sh., Kong, F., and Dong, Yi. 2010. Improvement of drainability of poplar APMP pulp by enzymes treatment. www.tappi.org/Downloads/ Conference-Papers/10PAP137.aspx.
[8]     Maximino, M.G., Taleb, M.C., Adell, A.M. and Formento, J.C. 2011. Application of Hydrolituc Enzymes and Refining on Recycled Fibers. Journal of Cellulose Chemistry and Technology. 45(5-6):397-403.
[9]     Gil, N., Gil, C., Amaral, M.E., Costa, A.P., and Duarte, A.P. 2009. Use of Enzymes to Improve the Reļ¬ning of a Bleached Eucalyptus Globulus Kraft Pulp. Biochemical Engineering Journal. 46: 89-95.
[10]  Oksanen, T., Pere, J., Paavilainen, L., J Buchert, J., and Viikari, L. 2000. Treatment of Recycled Kraft Pulps with Trichoderma Reesei Hemicellulases and Cellulases. Journal of Biotechnology. 78:39-48.
[11]  Barzan, A. 1998. Investigation of using packaging wastepaper to produce corrugated board in Mazandaran Wood and Paper Industry. M.Sc. Thesis, Tarbiat Modarres University. 95p.
[12]  Bhardwaj, N.K., Bajpai, P., and Bajpai, P.K. 1996. Use of Enzymes in Modification of Fibers for Improved Beatability. Journal of Biotechnology. 51: 21-26.
[13]  Mirshokrai, A. 2000. Handbook of pulp and paper technology (Translated in Persian). 2nd Ed., Aeazh, Tehran, 520p.
[14]  Afra, E. 2003. Properties of paper. Agricultural Sciences Press, 392p. (In Persian).
[15]  Akbarpour, I. 2011. Enzymatic deinking of old newspaper. M.Sc. Thesis, Gorgan University of Agricultural Sciences and Natural Resources.121p.
[16]  Kang, T. 2007. Role of External Fibrillation in Pulp and Paper Properties. Journal of P.A.J., 53(3): Pp 199.
[17]  Oksanen, T., Pere, J., Buchert, J., and Viikari, L. 1997. The Effect of Trichoderma Reesei Cellulases and Hemicellulases on the Paper Technical Properties of Never-Dried Bleached Kraft Pulp. Journal of Cellulose, 4:329-339.
[18]  Wong, K., Richardson, J., and Mansfield, Sh. 2000. Enzymatic Treatment on Mechanical Pulp Fibers for Improving Papermaking Properties. Journal of Biotechnol. Prog. 16:1025-1029.
[19]  Singh, R., and Bhardvaj. 2011. Enzymatic treatment of recycled fibers for improving of drainage: An overview, IPPTA j., 23(2):121-126.
[20]  Kibblewhite, R.P., and Wong, K.K.Y. 1999. Modification of a Aommercial Rdiate Pine Kraft Pulp Using Carbohydrate Degrading Enzymes. Appita Journal. 52(4), 300-304.
[21]  Lecourt, M., Sigoillot, J., and Petit-Conil, M. 2010. Cellulose-Assisted Refining of Chemical Pulp: Impact of Enzymatic Charge and Refining Intensity Consumption and Pulp Quality. Journal of Process Biochemistry, 45:1274-1278.
[22]  Clarc, T.A., Allison, R.W., and Kibblewhite, R.P. 1997. Effect of Enzymatic Modification on Radiate Pine Kraft Fiber Wall Chemistry and Physical Properties. Appita Journal, 50(4):329-335.
[23]  Bajpai, P., Mishra, Sh.P., Mishra, O.P., Kumar, S., and Bajpai, P.K. 2006. Use of Enzymesfor Reduction in Refining Energy-Laboratory Studies. Journal of Tappi. 5(11): 25-32.